Ketoximate Derivatives of Titanium Alkoxides and Partial Hydrolysis Products Thereof

被引：35

作者：

Baumann, Stefan O. ^{[1
]}

Bendova, Maria ^{[1
]}

Fric, Helmut ^{[1
]}

Puchberger, Michael ^{[1
]}

Visinescu, Claudia ^{[1
]}

Schubert, Ulrich ^{[1
]}

机构：

[1] Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 22期

基金：

奥地利科学基金会;

关键词：

Titanium; Oximate ligands; Metal Alkoxides; Partial hydrolysis; X-RAY STRUCTURES; STRUCTURAL CHEMISTRY; CRYSTAL-STRUCTURES; COMPLEXES; LIGANDS; OXIMES; TIO2;

D O I：

10.1002/ejic.200900381

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystalline oximate derivatives of titanium alkoxides [Ti(OR)(2)-(ON = CR'R '')(2)](2) were obtained when Ti(OR)(4) (R = iPr, Et) was treated with various oximes (cyclopentanone oxime, cyclohexanone oxime, acetoxime, ethyl methyl ketoxime or 2,4-pentandione dioxime). Formation of bis-substituted derivatives was favored in each case, and only one mono-substituted derivative, [Ti(OiPr)(3)(ON = C6H10)](2), was isolated. Two isomers were observed for [Ti(OR)(2)(ON = CR'R '')(2)](2), differing by the mutual orientation of the oximate ligands. The NO groups of the oximate ligands are side-on coordinated to one titanium atom in each case, Three partially hydrolyzed derivatives, viz. Ti6O6(OiPr)(6)(ON = CR2)(6) (CR2 = CMe2 or C5H8) and Ti4O2(OiPr)(8)(ON = CMe-CH2-CMe = NO)(2) were also structurally characterized. In these derivatives the NO groups bridge two titanium atoms. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：3333 / 3340

页数：8

共 35 条

[1] The reaction of iron carboxylates with titanium alkoxides.: Isolation and structural characterisation of [Ti6(μ3-O)6(O2CPh)6(OCH2C(CH3)3)6] [J].

Ammala, PS ;

Batten, SR ;

Kepert, CM ;

Spiccia, L ;

van den Bergen, AM ;

West, BO .

INORGANICA CHIMICA ACTA, 2003, 353 :75-81

[2]

BOUSQUEST EW, 1943, ORG SYNTH, V2, P313

[3] Formic acid modified Ti(OCHMe2)4.: Syntheses, characterization, and X-ray structures of Ti4(μ4-O)(μ-O)(OFc)2(μ-OR)4(OR)6 and Ti6(μ3-O)6(OFc)6(OR)6 (OFc = O2CH; OR = OCHMe2) [J].

Boyle, TJ ;

Alam, TM ;

Tafoya, CJ ;

Scott, BL .

INORGANIC CHEMISTRY, 1998, 37 (21) :5588-5594

[4] Implications for the thin-film densification of TiO2 from carboxylic acid-modified titanium alkoxides.: Syntheses, characterizations, X-ray structures of Ti3(μ3-O)(O2CH)2(ONep)8, Ti3(μ3-O)(O2CMe)2(ONep)8, Ti6(μ3-O)6(O2CCHMe2)6(ONep)6, [Ti(μ-O2CCMe3)(ONep)3]2, and Ti3(μ3-O)(O2CCH2CMe3)2(ONep)8 (ONep = OCH2CMe3) [J].

Boyle, TJ ;

Tyner, RP ;

Alam, TM ;

Scott, BL ;

Ziller, JW ;

Potter, BG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (51) :12104-12112

[5]

Bradley D. C, 2001, ALKOXO ARYLOXO DERIV

[6]

Bradley D.C., 1978, Metal alkoxides

[7] Complexation of titanium n-butoxide Ti(OBun)4 and zirconium n-butoxide Zr(OBun)4 with some oxime ligands and structural analysis of the complexes [J].

Buyuktas, BS ;

Aktas, O .

TRANSITION METAL CHEMISTRY, 2006, 31 (01) :56-61

[8] TUNGSTEN-CONTAINING POLYHEDRAL OLIGOSILASESQUIOXANES - SYNTHESIS, STRUCTURE AND REACTIVITY OF (C-C6H11)7SI7O9(O3W[NME2]3) [J].

CHISHOLM, MH ;

BUDZICHOWSKI, TA ;

FEHER, FJ ;

ZILLER, JW .

POLYHEDRON, 1992, 11 (13) :1575-1579

[9] Titanium(IV) complexes of oximes - Novel binding modes [J].

Davidson, Matthew G. ;

Johnson, Andrew L. ;

Jones, Matthew D. ;

Lunn, Matthew D. ;

Mahon, Mary F. .

POLYHEDRON, 2007, 26 (05) :975-980

[10] Organophosphonate derivatives of titanium and niobium alkoxoanions [J].

Errington, RJ ;

Ridland, J ;

Willett, KJ ;

Clegg, W ;

Coxall, RA ;

Heath, SL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) :473-476

← 1 2 3 4 →