The first electron-donor-acceptor paracyclophanes with ferrocene NLO-phores: Synthesis, absorption and electrochemical properties

被引：23

作者：

Kay, KY

Baek, YG

机构：

[1] Department of Chemistry, Ajou University

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 05期

关键词：

vinylferrocene; Pd-catalyzed twofold and fourfold couplings; electron-donor-acceptor[2.2]paracyclophanes; charge transfer; cyclic voltammetry;

D O I：

10.1002/cber.19971300508

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As potential nonlinear optical materials, 12-nitro-4,7-bis(2-ferrocenylvinyl)[2.2]paracyclophane (1) and 12-nitro-4,5,7,8-tetrakis(2-ferrocenylvinyl)[2.2]paracyclophane (2) have been synthesized by Pd-catalyzed coupling reactions of vinylferrocene with the precursor cyclophanes 9 and 13, respectively. The absorption and electrochemical properties of 1 and 2 are also described.

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页码：581 / 584

页数：4

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