One-Step Hydrothermal Synthesis of a Porous Cu2O Film and Its Photoelectrochemical Properties

被引：35

作者：

Ji, Ran ^{[1
]}

Sun, Wendong ^{[1
]}

Chu, Ying ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

来源：

CHEMPHYSCHEM | 2013年 / 14卷 / 17期

关键词：

Cu2O film; hydrothermal synthesis; photoelectrochemical properties; porous; redox chemistry; THIN-FILMS; CUPROUS-OXIDE; PHOTOCATALYTIC ACTIVITY; HOLLOW MICROSPHERES; COPPER; NANOCRYSTALS; NANOWIRES; NANOCUBES; ELECTRODES; DEPOSITION;

D O I：

10.1002/cphc.201300735

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

A cuprous oxide (Cu2O) film with a novel porous structure is successfully synthesized on Cu foil by using a simple hydrothermal method. A redox reaction occurs between Cu and Cu2+ in aqueous solution to form the Cu2O film. The porous structures are formed as a result of the Ostwald ripening mechanism. In addition, photoluminescence measurements indicate that the porous Cu2O film may reduce the recombination of photogenerated electrons and holes. The UV/Vis absorption property of the porous Cu2O film is better than that of the granular Cu2O film, and its high photocurrent is expected to make the porous Cu2O film more suitable for solar energy applications.

引用

页码：3971 / 3976

页数：6

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