The HNC/HCN ratio in comets

被引:21
作者
Irvine, WM [1 ]
Dickens, JE
Lovell, AJ
Schloerb, FP
Senay, M
Bergin, EA
Jewitt, D
Matthews, HE
机构
[1] Univ Massachusetts, Five Coll Radio Astron Observ, Amherst, MA 01003 USA
[2] Smithsonian Astrophys Observ, Cambridge, MA 02138 USA
[3] Univ Hawaii, Inst Astron, Honolulu, HI 96822 USA
[4] Joint Astron Ctr, Hilo, HI 96720 USA
来源
EARTH MOON AND PLANETS | 1997年 / 78卷 / 1-3期
关键词
comets; interstellar molecules;
D O I
10.1023/A:1006202823878
中图分类号
P1 [天文学];
学科分类号
0704 ;
摘要
The abundance ratio of the isomers HCN and HNC has been investigated in comet Hale-Bopp (C/1995 O1) through observations of the J = 4-3 rotational transitions of both species for heliocentric distances 0.93 < r<3 AU, both pre- and post-perihelion. After correcting for the optical depth of the stronger HCN line, we find that the column density ratio of HNC/HCN in our telescope beam increases significantly as the comet approaches the Sun. We compare this behavior to that predicted from an ion-molecule chemical model and conclude that the HNC is produced in significant measure by chemical processes in the coma; i.e., for comet Hale-Bopp, HNC is not a parent molecule sublimating from the nucleus.
引用
收藏
页码:29 / 35
页数:7
相关论文
共 19 条
[1]   GAS-PHASE CHEMISTRY IN DENSE INTERSTELLAR CLOUDS INCLUDING GRAIN SURFACE MOLECULAR DEPLETION AND DESORPTION [J].
BERGIN, EA ;
LANGER, WD ;
GOLDSMITH, PF .
ASTROPHYSICAL JOURNAL, 1995, 441 (01) :222-243
[2]   Evolution of the outgassing of comet Hale-Bopp (C/1995 O1) from radio observations [J].
Biver, N ;
BockeleeMorvan, D ;
Colom, P ;
Crovisier, J ;
Davies, JK ;
Dent, WRF ;
Despois, D ;
Gerard, E ;
Lellouch, E ;
Rauer, H ;
Moreno, R ;
Paubert, G .
SCIENCE, 1997, 275 (5308) :1915-1918
[3]   Long-term evolution of the outgassing of comet Hale-Bopp from radio observations [J].
Biver, N ;
Bockelée-Morvan, D ;
Colom, P ;
Crovisier, J ;
Germain, B ;
Lellouch, E ;
Davies, JK ;
Dent, WRF ;
Moreno, R ;
Paubert, G ;
Wink, J ;
Despois, D ;
Lis, DC ;
Mehringer, D ;
Benford, D ;
Gardner, M ;
Phillips, TG ;
Gunnarsson, M ;
Rickman, H ;
Winnberg, A ;
Bergman, P ;
Johansson, LEB ;
Rauer, H .
EARTH MOON AND PLANETS, 1997, 78 (1-3) :5-11
[4]   PRODUCTION OF INTERSTELLAR HCN AND HNC [J].
BROWN, RD ;
BURDEN, FR ;
CUNO, A .
ASTROPHYSICAL JOURNAL, 1989, 347 (02) :855-858
[6]   Abundances of HCN and HNC in dark cloud cores [J].
Hirota, T ;
Yamamoto, S ;
Mikami, H ;
Ohishi, M .
ASTROPHYSICAL JOURNAL, 1998, 503 (02) :717-728
[7]  
Irvine W.M., 1987, Interstellar Processes, P561, DOI [10.1007/978-94-009-3861-8_21, DOI 10.1007/978-94-009-3861-8_21]
[8]   Spectroscopic evidence for interstellar ices in comet Hyakutake [J].
Irvine, WM ;
BockeleeMorvan, D ;
Lis, DC ;
Matthews, HE ;
Biver, N ;
Crovisier, J ;
Davies, JK ;
Dent, WRF ;
Gautier, D ;
Godfrey, PD ;
Keene, J ;
Lovell, AJ ;
Owen, TC ;
Phillips, TG ;
Rauer, H ;
Schloerb, FP ;
Senay, M ;
Young, K .
NATURE, 1996, 383 (6599) :418-420
[9]   Chemistry in cometary comae [J].
Irvine, WM ;
Dickens, JE ;
Lovell, AJ ;
Schloerb, FP ;
Senay, M ;
Bergin, EA ;
Jewitt, D ;
Matthews, HE .
FARADAY DISCUSSIONS, 1998, 109 :475-492
[10]   CYANIDE AND ISOCYANIDE ABUNDANCES IN THE COLD, DARK CLOUD TMC-1 [J].
IRVINE, WM ;
SCHLOERB, FP .
ASTROPHYSICAL JOURNAL, 1984, 282 (02) :516-521