Electrochemical synthesis of polypyrrole and polythiophene in supercritical trifluoromethane

被引:16
作者
Atobe, M [1 ]
Ohsuka, H [1 ]
Fuchigami, T [1 ]
机构
[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
关键词
D O I
10.1246/cl.2004.618
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supercritical trifluoromethane (scCHF(3)) has been used as an electrolytic medium for the electrooxidative polymerization of pyrrole and thiophene; both monomers could be electropolymerized apparently faster in scCHF(3) than in the coventional organic media like an acetonitrile Solution, and the obtained films had highly-regulated structure.
引用
收藏
页码:618 / 619
页数:2
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