Rhodium catalysed tandem conjugate addition-protonation: an enantioselective synthesis of 2-substituted succinic esters

被引：52

作者：

Moss, RJ ^{[1
]}

Wadsworth, KJ ^{[1
]}

Chapman, CJ ^{[1
]}

Frost, CG ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 17期

关键词：

D O I：

10.1039/b406905f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rhodium catalysed addition of potassium trifluoro(organo) borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.

引用

页码：1984 / 1985

页数：2

共 15 条

[1] HOMOGENEOUS CATALYSIS - CATALYTIC PRODUCTION OF SIMPLE ENOLS
BERGENS, SH
BOSNICH, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) : 958 - 967
[2] Burk MJ, 1998, ANGEW CHEM INT EDIT, V37, P1931, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1931::AID-ANIE1931>3.0.CO
[3] 2-3
[4] Enantioselective rhodium-catalysed addition of boronic acids using C2-symmetric aryl diphosphite ligands
Chapman, CJ
Wadsworth, KJ
Frost, CG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 680 (1-2) : 206 - 211
[5] Potassium trifluoro(organo)borates: New perspectives in organic chemistry
Darses, S
Genet, JP
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (22) : 4313 - 4327
[6] Recent advances into the enantioselective protonation of prostereogenic enol derivatives
Eames, J
Weerasooriya, N
[J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (01) : 1 - 24
[7] Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds
Fagnou, K
Lautens, M
[J]. CHEMICAL REVIEWS, 2003, 103 (01) : 169 - 196
[8] Rhodium-catalyzed asymmetric conjugate addition of organoboronic acids to nitroalkenes
Hayashi, T
Senda, T
Ogasawara, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) : 10716 - 10717
[9] Hayashi T, 2001, SYNLETT, P879
[10] Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions
Hayashi, T
Yamasaki, K
[J]. CHEMICAL REVIEWS, 2003, 103 (08) : 2829 - 2844

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