Oxidation of primary alcohols to carboxylic acids using silica supported CrO3/H5IO6 under microwave irradiation in a solvent-free system

被引：7

作者：

Heravi, Majid M. ^{[1
]}

Farhangi, Nasrin

Bakhtiari, Khadijeh

Ghassemzadeh, Mitra

机构：

[1] Azzahra Univ, Sch Sci, Dept Chem, Tehran, Iran

[2] Chem & Chem Engn Res Ctr Iran, Tehran, Iran

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2006年 / 53卷 / 03期

关键词：

oxidation; primary alcohols; CrO3/periodic acid; wet silica gel; carboxylic acids; microwave irradiation;

D O I：

10.1002/jccs.200600085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chromium trioxide/periodic acid supported onto wet silica gel oxidizes primary alcohols to the corresponding carboxylic acids in very short reaction times in very good yields.

引用

页码：643 / 645

页数：3

共 27 条

[1]

[Anonymous], 1976, HDB CHEM PHYS

[2]

CAINELLI G, 1984, CHROMIUM OXIDATIONS, P118

[3] A GREATLY IMPROVED PROCEDURE FOR RUTHENIUM TETRAOXIDE CATALYZED OXIDATIONS OF ORGANIC-COMPOUNDS [J].

CARLSEN, PHJ ;

KATSUKI, T ;

MARTIN, VS ;

SHARPLESS, KB .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (19) :3936-3938

[4] Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide [J].

Das, S ;

Punniyamurthy, T .

TETRAHEDRON LETTERS, 2003, 44 (32) :6033-6035

[5]

deNooy AEJ, 1996, SYNTHESIS-STUTTGART, P1153

[6] Oxidative deprotection of tetrahydropyranyl ethers to carbonyl compounds with montmorillonite K-10 supported bis(trimethylsilyl) chromate under non-aqueous conditions [J].

Heravi, MM ;

Ajami, D .

JOURNAL OF CHEMICAL RESEARCH-S, 1998, (11) :718-719

[7]

Heravi MM, 1999, MONATSH CHEM, V130, P337, DOI 10.1007/PL00010215

[8] Ammonium chlorochromate adsorbed on montmorillonite K-10: Selective oxidation of alcohols under solvent-free conditions [J].

Heravi, MM ;

Kiakojoori, R ;

Hydar, KT .

JOURNAL OF CHEMICAL RESEARCH, 1998, (10) :656-657

[9] A convenient oxidative deprotection of tetrahydropyranyl ethers with iron(III) nitrate and clay under microwave irradiation in solvent free conditions [J].

Heravi, MM ;

Ajami, D ;

Mojtahedi, MM ;

Ghassemzadeh, M .

TETRAHEDRON LETTERS, 1999, 40 (03) :561-562

[10] Remarkable fast microwave-assisted zeolite HZSM-5 catalyzed oxidation of alcohols with chromium trioxide under solvent-free conditions [J].

Heravi, MM ;

Ajami, D ;

Tabar-Hydar, K ;

Ghassemzadeh, M .

JOURNAL OF CHEMICAL RESEARCH, 1999, (05) :334-335

← 1 2 3 →