Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide

被引：86

作者：

Das, S ^{[1
]}

Punniyamurthy, T ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Gauhati 781039, India

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 32期

关键词：

oxidation; alcohols; catalyst; hydrogen peroxide; cobalt(II) complex;

D O I：

10.1016/S0040-4039(03)01479-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidation of aliphatic and aromatic alcohols into the corresponding carboxylic acid analogues and ketones has been carried out using 30% H2O2 and cobalt(II) complex 1 in good to high yields. The reaction is safe, clean and functions in the absence of additives. (C) 2003 Elsevier Ltd. All rights reserved.

引用

收藏

页码：6033 / 6035

页数：3

相关论文

共 14 条

[1] Copper-catalyzed aerobic oxidation of alcohols under fluorous biphasic conditions [J].

Betzemeier, B ;

Cavazzini, M ;

Quici, S ;

Knochel, P .

TETRAHEDRON LETTERS, 2000, 41 (22) :4343-4346

[2] A GREATLY IMPROVED PROCEDURE FOR RUTHENIUM TETRAOXIDE CATALYZED OXIDATIONS OF ORGANIC-COMPOUNDS [J].

CARLSEN, PHJ ;

KATSUKI, T ;

MARTIN, VS ;

SHARPLESS, KB .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (19) :3936-3938

[3] Aerobic oxidation of primary alcohols (including methanol) by copper(II)- and zinc(II)-phenoxyl radical catalysts [J].

Chaudhuri, P ;

Hess, M ;

Müller, J ;

Hildenbrand, K ;

Bill, E ;

Weyhermüller, T ;

Wieghardt, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9599-9610

[4] Catalytic oxidation of alcohols into aldehydes and ketones by an osmium-copper bifunctional system using molecular oxygen [J].

Coleman, KS ;

Coppe, M ;

Thomas, C ;

Osborn, JA .

TETRAHEDRON LETTERS, 1999, 40 (19) :3723-3726

[5]

Dijksman A, 2001, SYNLETT, P102

[6] Efficient, ecologically benign, aerobic oxidation of alcohols [J].

Markó, IE ;

Giles, PR ;

Tsukazaki, M ;

Chellé-Regnaut, I ;

Gautier, A ;

Brown, SM ;

Urch, CJ .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (07) :2433-2439

[7] Catalytic asymmetric and chemoselective aerobic oxidation: kinetic resolution of sec-alcohols [J].

Masutani, K ;

Uchida, T ;

Irie, R ;

Katsuki, T .

TETRAHEDRON LETTERS, 2000, 41 (26) :5119-5123

[8] Chemoselective aerobic oxidation of primary alcohols catalyzed by a ruthenium complex [J].

Miyata, A ;

Murakami, M ;

Irie, R ;

Katsuki, T .

TETRAHEDRON LETTERS, 2001, 42 (40) :7067-7070

[9] COBALT(II) SCHIFFS BASE COMPLEX-CATALYZED OXIDATION OF ALCOHOLS WITH DIOXYGEN IN THE PRESENCE OF ETHYL 2-OXOCYCLOPENTANECARBOXYLATE [J].

PUNNIYAMURTHY, T ;

IQBAL, J .

TETRAHEDRON LETTERS, 1994, 35 (23) :4007-4010

[10] A functional model of galactose oxidase: catalytic oxidation of primary alcohols with a one-electron oxidized copper(II) complex [J].

Saint-Aman, E ;

Menage, S ;

Pierre, JL ;

Defrancq, E ;

Gellon, G .

NEW JOURNAL OF CHEMISTRY, 1998, 22 (05) :393-394