Ligand effects in the organolithium-mediated enantioselective alpha-deprotonation of achiral epoxides

被引：29

作者：

Hodgson, DM

Lee, GP

机构：

[1] Dyson Perrins Laboratory, University of Oxford, Oxford OX1 3QY, South Parks Road

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 14期

关键词：

D O I：

10.1016/S0957-4166(97)00262-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enantioselective alpha-deprotonation-rearrangement of achiral epoxides using organolithiums with C-2-symmetric ligands [bisoxazolines 4a-d and (-)-alpha-isosparteine 5] is described. (C) 1997 Elsevier Science Ltd.

引用

页码：2303 / 2306

页数：4

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