Aspects of immobilisation of catalysts on polymeric supports

被引:200
作者
Dioos, Bart M. L. [1 ]
Vankelecom, Ivo F. J. [1 ]
Jacobs, Pierre A. [1 ]
机构
[1] Katholieke Univ Leuven, Dept M2S, Ctr Oppervlaktechem & Katalyse, B-3001 Heverlee, Belgium
关键词
immobilisation; membranes; polymers; supported catalysts;
D O I
10.1002/adsc.200606202
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this review the authors intend to make a tutorial review on catalyst immobilisation from the viewpoint of the catalyst designer, emphasizing the use of promising concepts in this area, rather than trying to be exhaustive. The following topics are covered: 1 Introduction 2 Classic Ways of Immobilisation of Homogeneous Catalysts 3 General Remarks on Catalyst Heterogenisation on Polymeric Supports 3.1 Polymeric Supports 3.2 Polymer Supported Monodentate Phosphine Complexes 3.3 Polymer Supported Bidentate Phosphine Complexes 3.4 Phosphazene-Based Catalysts 3.5 Various Polymer Tethered Ligands with O or/and N as Metal Chelating Atoms 4 Recent Advances in Immobilisation of Chiral Catalysts
引用
收藏
页码:1413 / 1446
页数:34
相关论文
共 304 条
[1]   Recycling of the homogeneous Co-Jacobsen catalyst through solvent-resistent nanofiltration (SRNF) [J].
Aerts, S ;
Weyten, H ;
Buekenhoudt, A ;
Gevers, LEM ;
Vankelecom, IFJ ;
Jacobs, PA .
CHEMICAL COMMUNICATIONS, 2004, (06) :710-711
[2]  
AERTS S, IN PRESS J MEM SCI
[3]  
Ahmed M, 2000, SYNLETT, P1007
[4]   The polymer incarcerated method for the preparation of highly active heterogeneous palladium catalysts [J].
Akiyama, R ;
Kobayashi, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) :3412-3413
[5]   Synthesis of spherical particulate polysiloxane resins as catalyst supports [J].
Alder, KI ;
Sherrington, DC .
CHEMICAL COMMUNICATIONS, 1998, (01) :131-132
[6]   Supported chiral catalysts:: the role of the polymeric network [J].
Altava, B ;
Burguete, MI ;
García-Verdugo, E ;
Luis, SV ;
Vicent, MJ ;
Mayoral, JA .
REACTIVE & FUNCTIONAL POLYMERS, 2001, 48 (1-3) :25-35
[7]   Synthesis and catalytic activity of Fe(III) anchored to a polystyrene-Schiff base support [J].
Antony, R ;
Tembe, GL ;
Ravindanathan, M ;
Ram, RN .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 171 (1-2) :159-168
[8]   Effect of spacers on the activity of soluble polymer supported catalysts for the asymmetric addition of diethylzinc to aldehydes [J].
Anyanwu, UK ;
Venkataraman, D .
TETRAHEDRON LETTERS, 2003, 44 (34) :6445-6448
[9]   Catalyst analogue: A concept for constructing multicomponent asymmetric catalysts (MAC) by using a polymer support [J].
Arai, T ;
Sekiguti, T ;
Otsuki, K ;
Takizawa, S ;
Sasai, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (19) :2144-2147
[10]   Dendritic catalysts and dendrimers in catalysis [J].
Astruc, D ;
Chardac, F .
CHEMICAL REVIEWS, 2001, 101 (09) :2991-3023