A convenient method for production of thionitrites and disulfides under mild and heterogeneous condition

被引：42

作者：

Zolfigol, MA ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Coll Sci, Dept Chem, Hamadan 65174, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 09期

关键词：

D O I：

10.1080/00397910008087194

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thiols can be readily converted to their corresponding thionitrite with a combination of inorganic acidic salts and sodium nitrite in dichloromethane at room temperature. Disulfides result from the homolytic cleavage of the sulfur-nitrogen bond of the unstable thionitrite and subsequent coupling of the resultant thiyl radicals.

引用

页码：1593 / 1597

页数：5

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