Yttrium iodide and bis(trimethylsilyl)methyl complexes of the chelating diamide [ArN(CH2)3NAr]2- (Ar=2,6-iPr2C6H3)

被引:27
作者
Geoffrey, F [1 ]
Cloke, N [1 ]
Elvidge, BR [1 ]
Hitchcock, PB [1 ]
Lamarche, VME [1 ]
机构
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 12期
关键词
D O I
10.1039/b203757b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Yttrium triiodide reacts with the potassium salt K-2[ArN(CH2)(3)NAr] (Ar = 2,6-(Pr2C6H3)-Pr-i) to yield a mono-iodide complex and, by further reaction with K[CH(SiMe3)(2)], the corresponding alkyl complex, which have both been characterised by NMR spectroscopy and X-ray crystallography.
引用
收藏
页码:2413 / 2414
页数:2
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