A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand

被引：16

作者：

Adams, H ^{[1
]}

Bradshaw, D ^{[1
]}

Fenton, DE ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

POLYHEDRON | 2002年 / 21卷 / 19期

关键词：

crystal structures; zinc(II) complexes; co-ordination number asymmetry;

D O I：

10.1016/S0277-5387(02)01099-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the unsymmetrical compartmental proligand H2L3 with zinc(II) acetate and a counteranion to promote crystallisation has given the homodinuclear complexes [Zn2L3(OAc)(OH2)]X(.)nMeOH(.)mH(2)O [X = BF4, ClO4, PF6] which are co-ordination number asymmetric having present five- and six-co-ordinated zinc atoms. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1957 / 1960

页数：4

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