Synthesis and characterization of electrically conducting polyaniline in water-oil microemulsion

被引：75

作者：

Yan, F ^{[1
]}

Xue, G ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, Dept Polymer Sci, Nanjing 210093, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1999年 / 9卷 / 12期

关键词：

D O I：

10.1039/a905146e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanoscopic polyaniline particles were successfully synthesized in a stable water-oil microemulsion. FT-IR spectra showed that sodium dodecylbenzenesulfonate (SDBA) acted both as surfactant and dopant in the acidic reaction media. Wide-angle X-ray diffraction, UV-visible spectra and thermal analysis suggested that the crystallinity of PANI synthesized in the microemulsion system was increased dramatically while the chain-transfer reactions of co-surfactants decreased the pi-conjugation length along the polymer chain.

引用

页码：3035 / 3039

页数：5

共 46 条

[31]

Roy S, 1996, J APPL POLYM SCI, V62, P1509, DOI 10.1002/(SICI)1097-4628(19961205)62:10<1509::AID-APP3>3.0.CO

[32]

2-S

[33] STRUCTURAL AND ELECTRONIC-TRANSITIONS IN POLYANILINE - A FOURIER-TRANSFORM INFRARED SPECTROSCOPIC STUDY [J].

SARICIFTCI, NS ;

KUZMANY, H ;

NEUGEBAUER, H ;

NECKEL, A .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (07) :4530-4539

[34] PREPARATION AND PROPERTIES OF WATER-SOLUBLE, POLY(STYRENESULFONIC ACID)-DOPED POLYANILINE [J].

SHANNON, K ;

FERNANDEZ, JE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (05) :643-644

[35] Transport and structural properties of polyaniline doped with monovalent and multivalent ions [J].

Singh, R ;

Arora, V ;

Tandon, RP ;

Chandra, S ;

Kumar, N ;

Mansingh, A .

POLYMER, 1997, 38 (19) :4897-4902

[36] POLARON LATTICE IN HIGHLY CONDUCTING POLYANILINE - THEORETICAL AND OPTICAL STUDIES [J].

STAFSTROM, S ;

BREDAS, JL ;

EPSTEIN, AJ ;

WOO, HS ;

TANNER, DB ;

HUANG, WS ;

MACDIARMID, AG .

PHYSICAL REVIEW LETTERS, 1987, 59 (13) :1464-1467

[37] COLLOIDAL DISPERSIONS OF ELECTRICALLY-CONDUCTING, SPHERICAL POLYANILINE PARTICLES [J].

VINCENT, B ;

WATERSON, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (09) :683-684

[38]

WANG FS, 1988, MOL CRYST LIQ CRYST, V160, P175

[39]

WANG S, 1986, SYNTHETIC MET, V78, P1

[40]

WANG SL, 1986, SYNTHETIC MET, V16, P99, DOI 10.1016/0379-6779(86)90158-X

← 1 2 3 4 5 →