Influence of the age and drying process on pore structure and sorption isotherms of hardened cement paste

被引：120

作者：

Espinosa, Rosa Maria ^{[1
]}

Franke, Lutz ^{[1
]}

机构：

[1] Hamburg Univ Technol, Dept Bldg Phys & Bldg Mat, D-21071 Hamburg, Germany

来源：

CEMENT AND CONCRETE RESEARCH | 2006年 / 36卷 / 10期

关键词：

adsorption; desorption; hysteresis; change of pore structure; inkbottle pores;

D O I：

10.1016/j.cemconres.2006.06.010

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

Sorption isotherms and scanning-isotherms of hardened Portland cement paste were measured. A structure model was developed to give a theoretical interpretation for the measured sorption isotherms. In particular, the causes for hysteresis between adsorption and desorption were described. Not only the capillary effect between condensation and evaporation in the pores but also the chemical water uptake, the drying method and the chemical aging have to be considered to explain the significant hysteresis. These results are the basis of our model for the structure and the porosity change of cementitious materials. The mathematical implementation of the structure model (called IBP-method [R.M. Espinosa, Sorptionsisothermen von Zementstein und Wad, Dissertation Hamburg University of Technology, 2004.]) will be described in a further essay [R.M. Espinosa, L. Franke, Inkbottle Pore-Method: prediction of hygroscopic water content in hardened cement paste at variable climatic conditions, Cement and Concrete Research (2006-this issue) doi:10.1016/j.cemconres.2006.06.011]. (C) 2006 Published by Elsevier Ltd.

引用

页码：1969 / 1984

页数：16

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