Synthesis and characterization of R2SbH, R2BiH, and R2Bi-BiR2 [R = (Me3Si)2CH]

被引：46

作者：

Balázs, G ^{[1
]}

Breunig, HJ ^{[1
]}

Lork, E ^{[1
]}

机构：

[1] Univ Bremen, Fachbereich Chem 2, D-28334 Bremen, Germany

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 13期

关键词：

D O I：

10.1021/om020202z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

R2SbH (1) and R2BiH (2) [R = (Me3Si)(2)CH] are formed by reactions of the corresponding chlorides with LiAlH4. 1 is stable up to 100 degreesC. Decomposition of 2 at room temperature leads to R2Bi-BiR2 (3) and H-2. The crystal structure of 3 consists of molecules in a near trans conformation. H-1 NMR studies of 3 in C6D6 show that the diastereotopic Me3Si groups become equivalent with increasing concentration and temperature.

引用

页码：2584 / 2586

页数：3

共 34 条

[1] SECONDARY BONDING IN ORGANOBISMUTH COMPOUNDS - COMPARISON OF THE STRUCTURES OF 2,2',5,5'-TETRAMETHYL-1,1'-DIBISMAFERROCENE AND 2,2',5,5'-TETRAMETHYLBIBISMOLE [J].

ASHE, AJ ;

KAMPF, JW ;

PURANIK, DB ;

ALTAWEEL, SM .

ORGANOMETALLICS, 1992, 11 (08) :2743-2745

[2]

ASHE AJ, 1990, ADV ORGANOMET CHEM, V30, P77

[3] Two stable hydrides of antimony:: RSbH2 and R(H)Sb-Sb(H)R (R = (Me3Si)2CH) [J].

Balázs, G ;

Breunig, HJ ;

Lork, E ;

Offermann, W .

ORGANOMETALLICS, 2001, 20 (13) :2666-2668

[4]

BECKER G, 1992, UNKONVENTIONELLE WEC, P199

[5] The synthesis and characterization of isobutylantimony compounds [J].

Berry, A .

POLYHEDRON, 1999, 18 (20) :2609-2615

[6]

Breunig HJ, 1998, ANGEW CHEM INT EDIT, V37, P3175, DOI 10.1002/(SICI)1521-3773(19981204)37:22<3175::AID-ANIE3175>3.0.CO

[7]

2-M

[8] Reactions of Ph2SbH and p-TolSbH2 with organic compounds [J].

Breunig, HJ ;

Probst, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 571 (02) :297-303

[9]

BREUNIG HJ, 1994, CHEM ORGANIC ARSENIC, P441

[10]

BREUNIG HJ, 1998, ANGEW CHEM, V110, P3361

← 1 2 3 4 →