Isotopic labelling studies of the deaminative fragmentation of N-nitrosohydroxylamines and related compounds by kinetics, millimetre-wave spectroscopy and O-17 NMR spectroscopy

被引：5

作者：

Haider, J ^{[1
]}

Hill, MNS ^{[1
]}

Menneer, ID ^{[1
]}

Maskill, H ^{[1
]}

Smith, JG ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a703801a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nitrous oxide enriched with O-18 has been identified by millimetre-wave spectroscopy from the acid-induced hydrolysis of N-1-(2-adamantyl)-N-2-[O-18]hydroxpdiazen-1-ium N-1-oxide 2 which, along with O-17 NMR studies and an alpha-deuterium kinetic isotope effect of k(H)/k(D) = 0.98 (+/-0.02) for N-nitroso-N-(2-[2-H-2] adamantyl)-O-benzylhydroxylamine 4, confirms (i) that nitrous oxide is liberated in these reactions, and (ii) that the fragmentations in these reactions are step-wise and not concerted.

引用

页码：1571 / 1572

页数：2