Li diffusion and fullerene dynamics in lithium fulleride Li12C60 from inelastic neutron scattering experiments

被引：3

作者：

Cristofolini, L

Cicognani, G

Dianoux, AJ

Facci, P

Fontana, MP

Riccò, M

机构：

[1] Univ Parma, Dipartimento Fis, I-43100 Parma, Italy

[2] Univ Parma, INFM, I-43100 Parma, Italy

[3] INFM, F-38042 Grenoble, France

[4] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France

来源：

PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES | 1999年 / 79卷 / 11-12期

关键词：

D O I：

10.1080/13642819908223095

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We present results on the dynamics of the Li+ ions and of the C-60 molecular units in Li12C60 Obtained by INS and QENS experiments performed on IN6 (at the Institut Laue-Langevin) covering the temperature range 150 K to 600 K. The transition from the high temperature Fm (3) over bar m to the low temperature tetragonal structure of Li12C60 is accompanied by significant changes in the vibrational density of states (v-DOS). The role of the Li+ vibrational and diffusional motion in determining the changes in the overall v-DOS is investigated.

引用

页码：2065 / 2071

页数：7

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