Optically active metal nanoparticles

被引:292
作者
Noguez, Cecilia [1 ]
Garzon, Ignacio L. [1 ]
机构
[1] Univ Nacl Autonoma Mexico, Inst Fis, Mexico City 01000, DF, Mexico
基金
芬兰科学院;
关键词
GOLD CLUSTERS; (R; R)-TARTARIC ACID; CIRCULAR-DICHROISM; CHIRALITY; SIZE; NANOCLUSTERS; ENERGETICS; CATALYSIS; SURFACES; AU-34(-);
D O I
10.1039/b800404h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Optical activity and its relation with chiral metal nanoparticles are revised in this tutorial review. The experimental evidence as well as the different mechanisms to explain the optical activity of ligand-protected nanoparticles are described, emphasizing the aspects that provide insights into this novel phenomenon at the nanoscale. The perspectives of this research field and a list of unsolved problems are presented. This tutorial review provides information for an interdisciplinary community working in synthesis, characterization and utilization of chiral metal nanoparticles.
引用
收藏
页码:757 / 771
页数:15
相关论文
共 52 条
[1]  
Barlow SM, 2003, SURF SCI REP, V50, P201, DOI [10.1016/S0167-5729(03)00015-3, 10.1016/s0167-5729(03)00015-3]
[2]  
Barron L. D., 2004, MOL LIGHT SCATTERING
[3]   Structural evolution of smaller gold nanocrystals: The truncated decahedral motif [J].
Cleveland, CL ;
Landman, U ;
Schaaff, TG ;
Shafigullin, MN ;
Stephens, PW ;
Whetten, RL .
PHYSICAL REVIEW LETTERS, 1997, 79 (10) :1873-1876
[4]   Gold nanoparticles: Assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology [J].
Daniel, MC ;
Astruc, D .
CHEMICAL REVIEWS, 2004, 104 (01) :293-346
[5]   Chiral organometallic half-sandwich complexes with defined metal configuration [J].
Ganter, C .
CHEMICAL SOCIETY REVIEWS, 2003, 32 (03) :130-138
[6]   Do thiols merely passivate gold nanoclusters? [J].
Garzón, IL ;
Rovira, C ;
Michaelian, K ;
Beltrán, MR ;
Ordejón, P ;
Junquera, J ;
Sánchez-Portal, D ;
Artacho, E ;
Soler, JM .
PHYSICAL REVIEW LETTERS, 2000, 85 (24) :5250-5251
[7]   Structural and vibrational analysis of amorphous Au-55 clusters [J].
Garzon, IL ;
PosadaAmarillas, A .
PHYSICAL REVIEW B, 1996, 54 (16) :11796-11802
[8]   Lowest energy structures of gold nanoclusters [J].
Garzon, IL ;
Michaelian, K ;
Beltran, MR ;
Posada-Amarillas, A ;
Ordejon, P ;
Artacho, E ;
Sanchez-Portal, D ;
Soler, JM .
PHYSICAL REVIEW LETTERS, 1998, 81 (08) :1600-1603
[9]   Chirality, defects, and disorder in gold clusters [J].
Garzón, IL ;
Beltrán, MR ;
González, G ;
Gutíerrez-González, I ;
Michaelian, K ;
Reyes-Nava, JA ;
Rodríguez-Hernández, JI .
EUROPEAN PHYSICAL JOURNAL D, 2003, 24 (1-3) :105-109
[10]   Chirality in bare and passivated gold nanoclusters -: art. no. 073403 [J].
Garzón, IL ;
Reyes-Nava, JA ;
Rodríguez-Hernández, JI ;
Sigal, I ;
Beltrán, MR ;
Michaelian, K .
PHYSICAL REVIEW B, 2002, 66 (07) :734031-734034