High Proton Conductivity of One-Dimensional Ferrous Oxalate Dihydrate

被引：324

作者：

Yamada, Teppei ^{[1
]}

Sadakiyo, Masaaki ^{[1
]}

Kitagawa, Hiroshi ^{[1
,2
]}

机构：

[1] Kyushu Univ, Fac Sci, Dept Chem, Fukuoka 8128581, Japan

[2] JST CREST, Higashi Ku, Fukuoka 8128581, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 09期

关键词：

METAL-ORGANIC FRAMEWORK; COPPER COORDINATION POLYMER; SMALL-ANGLE SCATTERING; IONIC-CONDUCTIVITY; SOLID-STATE; NANOSTRUCTURED MATERIALS; DEFECT CHEMISTRY; TRANSPORT; HYDROGEN; ADSORPTION;

D O I：

10.1021/ja808681m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Proton conductive materials become important for their utility to electrolytes of fuel cells or sensors. The proton conductivity of a one-dimensional coordination polymer, ferrous oxalate dihydrate, was evaluated and found to show 1.3 mS cm(-1) at ambient temperature. The proton conductivity of this compound is extremely high at ambient temperature without any strong acidic group, and this result is suggestive of new proton conductive materials consisting of coordination polymers.

引用

页码：3144 / +

页数：3