Continuous synthesis of NaA zeolite membranes

被引:42
作者
Aguado, Sonia [1 ]
Gascon, Jorge [1 ]
Jansen, Jacobus C. [1 ]
Kapteijn, Freek [1 ]
机构
[1] Delft Univ Technol, NL-2628 BL Delft, Netherlands
关键词
Zeolite NaA membrane; Continuous synthesis; Flow system; Pervaporation; INORGANIC MEMBRANES; GAS PERMEATION; A MEMBRANES; FLOW SYSTEM; PERVAPORATION; SEPARATION; PERFORMANCE; MIXTURES; COATINGS; SUPPORTS;
D O I
10.1016/j.micromeso.2008.08.062
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Zeolite NaA membranes were obtained by using a continuous recirculating flow, 0.25-5 ml min(-1) of synthesis solution along the inner side of asymmetric porous alumina tubular supports. The membranes of 5 mu m in thickness showed a N(2) permeance of 5 x 10(-7)-1 X 10(-6) mol m(-2) s(-1) Pa(-1). The procedure developed in this work provides control of the synthesis and crystallization conditions at any position on the tubular support, thus implying scale-up. (C) 2008 Elsevier Inc. All rights reserved.
引用
收藏
页码:170 / 176
页数:7
相关论文
共 33 条
[1]   Zeolite coatings on three-dimensional objects via laser ablation [J].
Balkus, KJ ;
Scott, AS .
CHEMISTRY OF MATERIALS, 1999, 11 (02) :189-191
[2]   Deposition of oriented zeolite A films: in situ and secondary growth [J].
Boudreau, LC ;
Kuck, JA ;
Tsapatsis, M .
JOURNAL OF MEMBRANE SCIENCE, 1999, 152 (01) :41-59
[3]  
Breck D.W.., 1974, J CHROMATOGR SCI, P55
[4]   Zeolite membranes -: state of their development and perspective [J].
Caro, J ;
Noack, M ;
Kölsch, P ;
Schäfer, R .
MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 38 (01) :3-24
[5]   Zeolite membranes:: From the laboratory scale to technical applications [J].
Caro, J ;
Noack, M ;
Kölsch, P .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2005, 11 (3-4) :215-227
[6]   Preparation of MFI type zeolite membranes in a flow system with circulation of the synthesis solution [J].
Culfaz, Pinar Zeynep ;
Qulfaz, Ali ;
Kalipcilar, Halil .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 92 (1-3) :134-144
[7]  
Giannetto G., 1985, ZEOLITE SYNTHESIS ST, P631
[8]   Electrophoretic technique for hydrothermal synthesis of NaA zeolite membranes on porous α-Al2O3 supports [J].
Huang, Aisheng ;
Yang, Weishen .
MATERIALS RESEARCH BULLETIN, 2007, 42 (04) :657-665
[9]   Separation of alcohol/water mixtures by pervaporation through zeolite A membranes [J].
Jafar, JJ ;
Budd, PM .
MICROPOROUS MATERIALS, 1997, 12 (4-6) :305-311
[10]  
JANSEN JC, 1994, STUD SURF SCI CATAL, V85, P215