The effect of pH on the emission and absorption spectra of a ruthenium complex

被引:14
作者
Ellerbrock, JC [1 ]
McLoughlin, SM [1 ]
Baba, AI [1 ]
机构
[1] Xavier Univ, Dept Chem, Cincinnati, OH 45207 USA
关键词
phenanthroline; ligand; ruthenium; pH; spectroscopic; sensor;
D O I
10.1016/S1387-7003(02)00480-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A ruthenium complex, Ru(Phen)(2)(Phen--OH-CO2Et)(2+) (PF6)(2), where Phen = 1,10-phenanthroline and Phen--OH-CO2Et = 3-carbethoxy,4-hydroxy-1,10-phenanthroline ligands has been synthesized. The emission intensity of this complex changes in the pH range of 3-11, which makes it useful in the design of chemosensors. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:555 / 559
页数:5
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