Fluctuation theorem for nonequilibrium reactions

被引：213

作者：

Gaspard, P ^{[1
]}

机构：

[1] Free Univ Brussels, Ctr Nonlinear Phenomena & Complex Syst, B-1050 Brussels, Belgium

来源：

JOURNAL OF CHEMICAL PHYSICS | 2004年 / 120卷 / 19期

关键词：

D O I：

10.1063/1.1688758

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A fluctuation theorem is derived for stochastic nonequilibrium reactions ruled by the chemical master equation. The theorem is expressed in terms of the generating and large-deviation functions characterizing the fluctuations of a quantity which measures the loss of detailed balance out of thermodynamic equilibrium. The relationship to entropy production is established and discussed. The fluctuation theorem is verified in the Schlogl model of far-from-equilibrium bistability. (C) 2004 American Institute of Physics.

引用

页码：8898 / 8905

页数：8

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