Phosphoryldithioformates: Part V. Unusual linewidth variations in the ESR spectra of some spin adducts of (dimenthoxy)phosphoryl methyl dithioformate

被引：3

作者：

Alberti, A

Benaglia, M

Macciantelli, D

Hudson, A

Masson, S

机构：

[1] CNR, ISOF, I-40129 Bologna, Italy

[2] ISMRA Univ Caen, UMR 6507, Lab Chim Mol & Thio Organ, F-1450 Caen, France

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 2002年 / 40卷 / 06期

关键词：

ESR; H-1; C-13; phosphoryldithioformates; molecular tumbling; hindered rotation;

D O I：

10.1002/mrc.1032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unusual temperature-dependent linewidth variations were observed in spin adducts of (dimenthoxy)phosphoryl methyl dithioformate with bulky free radicals, possibly involving a combination of restricted rotation of a methyl group and slow molecular tumbling. Copyright (C) 2002 John Wiley Sons, Ltd.

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页码：387 / 390

页数：4

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