Chemistry of thiacalixarenes

被引:355
作者
Lhoták, P [1 ]
机构
[1] Prague Inst Chem Technol, Dept Organ Chem, CR-16628 Prague 6, Czech Republic
关键词
thiacalixarenes; supramolecular chemistry; stereochemistry; X-ray diffraction;
D O I
10.1002/ejoc.200300492
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Thiacalixarenes - new members of the calixarene family are very promising molecules with many potential applications in supramolecular chemistry. The presence of four sulfur atoms in the place of methylene groups imparts many novel features and properties to these molecules. This review deals with the chemistry of thiacalixarenes, and by comparision with "classical" calixarenes, emphasizes their differences in reactivity, unusual conformational preferences and modified complexation abilities. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码:1675 / 1692
页数:18
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