Solubility of amino acids and diglycine in aqueous-alkanol solutions

被引:68
作者
Ferreira, LA
Macedo, EA
Pinho, SP
机构
[1] Escola Super Tecnol Gestao, Inst Politecn Braganca, Lab Separat & React Engn, P-5301857 Braganca, Portugal
[2] Fac Engn, Dept Engn Quim, Lab Separat & React Engn, P-4200465 Oporto, Portugal
关键词
amino acid; phase equilibria; mixed solvents; modelling;
D O I
10.1016/j.ces.2004.05.001
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The solubility of glycine and dl-alanine were measured in the temperature range between 25degreesC and 60degreesC for the aqueous systems of ethanol, 1-propanol and 2-propanol. The analytical gravimetric method was chosen to perform the measurements and proved to be very accurate. Theoretical work was essentially focused on the application of the excess solubility approach with the NRTL model showing average relative deviations around 8.4% for correlation and 15% for predictions. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3117 / 3124
页数:8
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