A compact, trinuclear, circular helicate with oxine-based N,O-chelating binding domains

被引:14
作者
Al-Mandhary, MRA
Steel, PJ
机构
[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand
[2] Sultan Qaboos Univ, Coll Sci, Al Khoud 123, Oman
关键词
D O I
10.1016/S1387-7003(02)00611-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The preparation of a silver triflate complex (5) of 1,3-bis(8-quinolyloxymethyl)benzene (4) is described. An X-ray crystal structure determination reveals that it is a compact circular helicate in which three silver atoms are bridged by three ligands in a cyclic array, with additional stabilisation via intramolecular pi-pi stacking interactions. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:954 / 957
页数:4
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