Optical and electrical properties of conjugated oligo(arylenes)

被引:4
作者
Czerwinski, W [1 ]
Lindén, LÅ
Rabek, JF
机构
[1] Nicholas Copernicus Univ, Fac Chem, PL-87100 Torun, Poland
[2] Karolinska Inst, Royal Acad Med, Dept Dent Biomat Sci, Polymer Res Grp, S-14104 Huddinge, Sweden
关键词
D O I
10.1023/A:1004779620005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
New conductive soluble oligo(p-phenylene), oligo(thiophene), oligo(p-phenylene-thiophene) (4 : 1) (1 : 1) (1 : 4), oligo(p-phenylene-sulphide), oligo(p-phenylene-selenide), oligo(p-diphenylene-sulphide) and oligo(p-diphenylene selenide) were synthesized. Structural, optical and electrical characteristics of these oligomers have been determined. The optical and electrical properties are dependent on the oligomers' structures. The conductivities of these oligomers are low, between 10(-4) and 10(-12) S m(-1). However, there is an increase after doping them with iodine. These soluble oligomers can be used for production of active components in opto-electronic devices. (C) 2000 Kluwer Academic Publishers.
引用
收藏
页码:455 / 463
页数:9
相关论文
共 40 条
[1]  
ABELES B., 1976, APPL SOLID STATE SCI, V6, P1, DOI 10.1016/B978-0-12-002906- 8.50007-X
[2]   CORRELATION BETWEEN VIBRATIONAL-SPECTRA AND ELECTRICAL-CONDUCTIVITY OF POLYTHIOPHENE [J].
AKIMOTO, M ;
FURUKAWA, Y ;
TAKEUCHI, H ;
HARADA, I ;
SOMA, Y ;
SOMA, M .
SYNTHETIC METALS, 1986, 15 (04) :353-360
[3]  
[Anonymous], 1991, Conjugated Polymers: The Novel Science and Technology of Highly Conducting and Nonlinear Optically Active Material
[4]   PHOTOEXCITATIONS IN CONJUGATED COPOLYMERS [J].
BOTTA, C ;
ROSSI, L ;
DESTRI, S ;
TUBINO, R .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1994, 256 :481-486
[5]  
BRADLEY DDC, 1992, SPRINGER SERIES SOLI, V107, P304
[6]   NEW SEMICONDUCTOR-DEVICE PHYSICS IN POLYMER DIODES AND TRANSISTORS [J].
BURROUGHES, JH ;
JONES, CA ;
FRIEND, RH .
NATURE, 1988, 335 (6186) :137-141
[7]   SMALL-BANDGAP CONDUCTING POLYMERS-BASED ON CONJUGATED POLY(HETEROARYLENE METHINES) .2. SYNTHESIS, STRUCTURE, AND PROPERTIES [J].
CHEN, WC ;
JENEKHE, SA .
MACROMOLECULES, 1995, 28 (02) :465-480
[8]   ELECTRONIC-STRUCTURE OF COPOLYMERS BASED ON PHENYLENE AND THIOPHENE UNITS [J].
CZERWINSKI, W ;
NUCKER, N ;
FINK, J .
SYNTHETIC METALS, 1988, 25 (01) :71-77
[9]   ELECTRONIC-PROPERTIES OF RANDOM-SEQUENCED COPOLYMERS [J].
CZERWINSKI, W .
SYNTHETIC METALS, 1990, 35 (1-2) :229-237
[10]  
CZERWINSKI W, 1987, SPRINGER SERIES SOLI, P330