Reactivity of the iron porphyrin Fe(TPP)(NO) with excess NO.: Formation of Fe(TPP)(NO)(NO2) occurs via reaction with trace NO2

被引：58

作者：

Lorkovic, IM ^{[1
]}

Ford, PC ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 04期

关键词：

D O I：

10.1021/ic9910413

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fe(TPP)(NO) (TPP = tetraphenylporphyrinato dianion) does not react observably with excess NO in organic solvents at ambient pressure and temperature; however, adventitious NO2 rapidly leads to the nitrosyl nitro product Fe(TPP)(NO)(NO2), which is labile toward loss of Nd. [GRAPHICS]

引用

页码：632 / +

页数：3

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