Poly(vinyl alcohol) star polymers prepared via MADIX/RAFT polymerisation

被引:126
作者
Stenzel, MH [1 ]
Davis, TP [1 ]
Barner-Kowollik, C [1 ]
机构
[1] Univ New S Wales, Sch Chem Engn & Ind Chem, Ctr Adv Macromol Design, Sydney, NSW 2031, Australia
关键词
D O I
10.1039/b404763j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(vinyl acetate) stars were prepared using MADIX/RAFT polymerisation mediated by xanthates. The polymerisation shows living characteristics with molecular weight increasing with conversion. The subsequent hydrolysis of these three and four arm stars led to the formation of poly(vinyl alcohol) stars.
引用
收藏
页码:1546 / 1547
页数:2
相关论文
共 17 条
[1]   RAFTing down under: Tales of missing radicals, fancy architectures, and mysterious holes [J].
Barner-Kowollik, C ;
Davis, TP ;
Heuts, JPA ;
Stenzel, MH ;
Vana, P ;
Whittaker, M .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (03) :365-375
[2]   Biodegradation of poly (vinyl alcohol) based materials [J].
Chiellini, E ;
Corti, A ;
D'Antone, S ;
Solaro, R .
PROGRESS IN POLYMER SCIENCE, 2003, 28 (06) :963-1014
[3]   A CONVENIENT SOURCE OF ALKYL AND ACYL RADICALS [J].
DELDUC, P ;
TAILHAN, C ;
ZARD, SZ .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (04) :308-310
[4]  
Destarac M, 2000, MACROMOL RAPID COMM, V21, P1035, DOI 10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO
[5]  
2-5
[6]   A detailed on-line FT/NIR and 1H NMR spectroscopic investigation into factors causing inhibition in xanthate-mediated vinyl acetate polymerization [J].
Favier, A ;
Barner-Kowollik, C ;
Davis, TP ;
Stenzel, MH .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2004, 205 (07) :925-936
[7]  
Mammen M, 1998, ANGEW CHEM INT EDIT, V37, P2755
[8]   Living radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization) using dithiocarbamates as chain transfer agents [J].
Mayadunne, RTA ;
Rizzardo, E ;
Chiefari, J ;
Chong, YK ;
Moad, G ;
Thang, SH .
MACROMOLECULES, 1999, 32 (21) :6977-6980
[9]  
MERRILL EW, 1993, J BIOMAT SCI-POLYM E, V5, P1
[10]  
NAGANO K, 1970, POLYVINYL ALCOHOL