Polymer intercalation in mesostructured carbon

被引：27

作者：

Kim, CH

Kim, SS

Guo, F

Hogan, TP

Pinnavaia, TJ ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

[2] Chongqing Univ, Dept Chem, Chonju 360764, South Korea

[3] Dept Elect & Comp Engn, E Lansing, MI 48824 USA

来源：

ADVANCED MATERIALS | 2004年 / 16卷 / 08期

关键词：

D O I：

10.1002/adma.200305692

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The intercalation of polypyrrole (ppy) into hexagonal mesostructured carbon at 6.80-1.2.6 wt.-% levels results in substantial shrinkage of the framework structure (Deltad(100) = 0.8-1.0 nm) and the pore size (from 3.7 nm initially to 2.9-2.5 nm upon ppy binding). The surface areas (718-960 m(2)g(-1)) and electrical conductivities (0.1-1.0 S cm(-1)) for compressed powders, however, are largely retained over a wide temperature range, providing potential applications in sensing.

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页码：736 / +

页数：5

相关论文

共 32 条

[1] OPTIMUM REACTION CONDITIONS FOR THE POLYMERIZATION OF PYRROLE BY IRON(III) CHLORIDE IN AQUEOUS-SOLUTION [J].

ARMES, SP .

SYNTHETIC METALS, 1987, 20 (03) :365-371

[2] Ordered nanoporous polymer-carbon composites [J].

Choi, M ;

Ryoo, R .

NATURE MATERIALS, 2003, 2 (07) :473-476

[3] Synthesis of a new polyaniline/nanotube composite:: "in-situ" polymerisation and charge transfer through site-selective interaction [J].

Cochet, M ;

Maser, WK ;

Benito, AM ;

Callejas, MA ;

Martínez, MT ;

Benoit, JM ;

Schreiber, J ;

Chauvet, O .

CHEMICAL COMMUNICATIONS, 2001, (16) :1450-1451

[4] Carbon materials for lithium-ion rechargeable batteries [J].

Flandrois, S ;

Simon, B .

CARBON, 1999, 37 (02) :165-180

[5]

Geng HZ, 2002, ADV MATER, V14, P1387, DOI 10.1002/1521-4095(20021002)14:19<1387::AID-ADMA1387>3.0.CO

[6]

2-Q

[7] Electrochemical insertion of lithium ions into disordered carbons derived from reduced graphite fluoride [J].

Giraudet, J ;

Dubois, M ;

Inacio, J ;

Hamwi, A .

CARBON, 2003, 41 (03) :453-463

[8] Dynamic mechanical behavior of in situ functionalized multi-walled carbon nano tube/phenoxy resin composite [J].

Goh, HW ;

Goh, SH ;

Xu, GQ ;

Pramoda, KP ;

Zhang, WD .

CHEMICAL PHYSICS LETTERS, 2003, 373 (3-4) :277-283

[9]

HAN S, 1999, CHEM COMMUN, P2177

[10] Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure [J].

Jun, S ;

Joo, SH ;

Ryoo, R ;

Kruk, M ;

Jaroniec, M ;

Liu, Z ;

Ohsuna, T ;

Terasaki, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) :10712-10713

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