Efficient Polymer Solar Cells Based on Benzothiadiazole and Alkylphenyl Substituted Benzodithiophene with a Power Conversion Efficiency over 8%

被引:318
作者
Zhang, Maojie [1 ]
Gu, Yu [2 ]
Guo, Xia [1 ]
Liu, Feng [2 ]
Zhang, Shaoqing [1 ]
Huo, Lijun [1 ]
Russell, Thomas P. [2 ]
Hou, Jianhui [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[2] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
基金
美国国家科学基金会;
关键词
benzothiadiazole; benzodithiophene; polymer solar cells; morphology; power conversion efficiency; OPEN-CIRCUIT VOLTAGE; HIGHLY EFFICIENT; PHOTOVOLTAIC PROPERTIES; FLUORINE SUBSTITUENTS; TANDEM POLYMER; SIDE-CHAINS; PERFORMANCE; DESIGN; ACCEPTOR; MORPHOLOGY;
D O I
10.1002/adma.201301494
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new copolymer PBDTP-DTBT based on benzothiadiazole and alkylphenyl substituted benzodithiophene is synthesized and characterized. The correlation of the evolution of the morphology and photovoltaic performance is investigated. The power conversion efficiency of the polymer solar cells based on PBDTP-DTBT/PC71BM (1:1.5, w/w) reaches up to 8.07%, under the irradiation of AM 1.5G, 100 mW/cm2. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4944 / 4949
页数:6
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