A chromoreactand for optical sensing of amphetamines

被引:20
作者
Mohr, GJ
Wenzel, M
Lehmann, F
Czerney, P
机构
[1] Univ Jena, Inst Phys Chem, D-07743 Jena, Germany
[2] Dyom GMBH, D-07745 Jena, Germany
关键词
optical sensor; reactand; amphetamine;
D O I
10.1007/s00216-002-1519-0
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A bisazo dye is presented that undergoes a reversible chemical reaction with amphetamine in thin layers of plasticised PVC and changes its colour from blue to red. The sensitivity of the dye in the polymer layer covers the range from 0.3 to 30 mmol L-1 amphetamine with a limit of detection of 0.1 mmol L-1. The maximum signal changes are observed at 630 nm making the dye compatible with cheap light sources and detectors.
引用
收藏
页码:399 / 402
页数:4
相关论文
共 37 条
[1]   4-vinylazobenzene: Polymerizability and photochromic properties of its polymers [J].
Altomare, A ;
Ciardelli, F ;
Tirelli, N ;
Solaro, R .
MACROMOLECULES, 1997, 30 (05) :1298-1303
[2]  
[Anonymous], 1990, SIGMA ALDRICH HDB ST
[3]   A hydrogen-bonding receptor that binds urea with high affinity [J].
Bell, TW ;
Hou, Z .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (13-14) :1536-1538
[4]   CROSS-LINKED POLYMER MATERIALS FOR NONLINEAR OPTICS .1. UV-CURED ACRYLIC-MONOMERS BEARING AZOBENZENE DYES [J].
BOOGERS, JAF ;
KLAASE, PTA ;
DEVLIEGER, JJ ;
ALKEMA, DPW ;
TINNEMANS, AHA .
MACROMOLECULES, 1994, 27 (01) :197-204
[5]   AZO POLYMERS FOR REVERSIBLE OPTICAL STORAGE .5. ORIENTATION AND DIPOLAR INTERACTIONS OF AZOBENZENE SIDE-GROUPS IN COPOLYMERS AND BLENDS CONTAINING METHYL-METHACRYLATE STRUCTURAL UNITS [J].
BROWN, D ;
NATANSOHN, A ;
ROCHON, P .
MACROMOLECULES, 1995, 28 (18) :6116-6123
[6]   Response function and analytical parameters of nitrite-selective optode membranes in absorbance and fluorescence mode [J].
Demuth, C ;
Spichiger, UE .
ANALYTICA CHIMICA ACTA, 1997, 355 (2-3) :259-268
[7]  
DeTuri MA, 1998, ABSTR PAP AM CHEM S, V215, pU16
[8]   A NEW SYNTHESIS OF KETONES CONTAINING ONE PERFLUOROALKYL GROUP [J].
DISHART, KT ;
LEVINE, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (10) :2268-2270
[9]   PLASTICIZERS FOR LIQUID POLYMERIC MEMBRANES OF ION-SELECTIVE CHEMICAL SENSORS [J].
EUGSTER, R ;
ROSATZIN, T ;
RUSTERHOLZ, B ;
AEBERSOLD, B ;
PEDRAZZA, U ;
RUEGG, D ;
SCHMID, A ;
SPICHIGER, UE ;
SIMON, W .
ANALYTICA CHIMICA ACTA, 1994, 289 (01) :1-13
[10]  
FIERZDAVID HE, 1946, GRUNDLEGENDE OPERATI