Indenylidene-imidazolylidene complexes of ruthenium as ring-closing metathesis catalysts

被引:212
作者
Jafarpour, L [1 ]
Schanz, HJ [1 ]
Stevens, ED [1 ]
Nolan, SP [1 ]
机构
[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
关键词
D O I
10.1021/om990587u
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The indenylidene-imidazolylidene complexes of ruthenium (IMes)(PR3)Cl2Ru(3-phenylindenylid-1-ene) and (IPr)(PR3)Cl2Ru(3-phenylindenylid-1-ene) (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, IPr = 1,3-bis(2, 6-diisopropylphenyl)imidazol-2-ylidene and R = Ph, Cy) were prepared and found to be efficient catalyst precursors for ring-closing metathesis.
引用
收藏
页码:5416 / 5419
页数:4
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