Surface morphology and crystallinity of biaxially stretched PET films on the nanoscale

被引:26
作者
Dinelli, F [1 ]
Assender, HE [1 ]
Kirov, K [1 ]
Kolosov, OV [1 ]
机构
[1] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
关键词
poly(ethylene terephthalate); scanning probe microscopy; crystallinity;
D O I
10.1016/S0032-3861(99)00500-5
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The surface morphology and crystallinity of biaxially drawn (BD) and amorphous poly(ethylene terephthalate) (PET) films were investigated by means of scanning probe microscopy. The PET surface is best imaged using non-contact mode atomic force microscopy (NC-AFM). Contact mode (C-AFM) under water can also offer a good resolution but the PET surface is not stable for long periods under such conditions. The ED film texture appears to be made up of "hillocks" of about 20 nm in diameter, while amorphous PET films appear featureless. It seems plausible to suggest that the observed hillocks represent small crystallites formed during the production process of BD films. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4285 / 4289
页数:5
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