Fullerene grafted hydrocarbon polymers

被引：19

作者：

Patil, AO

Brois, SJ

机构：

[1] Corporate Research Laboratory, Exxon Res. and Engineering Company, Annandale, NJ 08801, Route 22 East, Clinton Township

来源：

POLYMER | 1997年 / 38卷 / 13期

关键词：

fullerenes; C-60; graft copolymer; function polymers;

D O I：

10.1016/S0032-3861(97)00032-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We have free radically grafted fullerene onto saturated hydrocarbon polymers such as ethylene-propylene copolymer. The product is soluble in solvents such as hexane or tetrahydrofuran, in which the fullerene is essentially insoluble. The reaction of the fullerene and polymer was followed by i.r. spectroscopy and gel permeation chromatography. In these graft copolymers, fullerene may provide sites for further derivatization, including derivatization by methods which would fail for the original polymer. (C) 1997 Elsevier Science Ltd.

引用

页码：3423 / 3424

页数：2

共 11 条

[1] FULLERENE-STYRENE RANDOM COPOLYMERS - NOVEL OPTICAL-PROPERTIES [J].

BUNKER, CE ;

LAWSON, GE ;

SUN, YP .

MACROMOLECULES, 1995, 28 (10) :3744-3746

[2] FREE-RADICAL COPOLYMERIZATION OF FULLERENES WITH STYRENE [J].

CAO, T ;

WEBBER, SE .

MACROMOLECULES, 1995, 28 (10) :3741-3743

[3]

DATTA S, 1992, POLYM PREPR AM CHEM, V33, P899

[4]

GECKELER KE, 1994, TRENDS POLYM SCI, V2, P355

[5] FULLERENES C60 AND C70 IN FLAMES [J].

HOWARD, JB ;

MCKINNON, JT ;

MAKAROVSKY, Y ;

LAFLEUR, AL ;

JOHNSON, ME .

NATURE, 1991, 352 (6331) :139-141

[6] SOLID C-60 - A NEW FORM OF CARBON [J].

KRATSCHMER, W ;

LAMB, LD ;

FOSTIROPOULOS, K ;

HUFFMAN, DR .

NATURE, 1990, 347 (6291) :354-358

[7] SYNTHESIS OF A C-60-P-XYLYLENE COPOLYMER [J].

LOY, DA ;

ASSINK, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (10) :3977-3978

[8]

PATIL AO, 1996, POLYM MAT ENCY SYNTH, V4, P2597

[9] THE CHEMISTRY OF FULLERENES [J].

TAYLOR, R ;

WALTON, DRM .

NATURE, 1993, 363 (6431) :685-693

[10] THE CHEMICAL-PROPERTIES OF BUCKMINSTERFULLERENE (C-60) AND THE BIRTH AND INFANCY OF FULLEROIDS [J].

WUDL, F .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (03) :157-161

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