Sulfated CexZr1-xO2 solid acid catalyst for solvent free synthesis of coumarins

被引：54

作者：

Reddy, Benjaram M. ^{[1
]}

Patil, Meghshyam K. ^{[1
]}

Lakshmanan, Pandian ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 256卷 / 1-2期

关键词：

solid acid; sulfated ceria-zirconia; acid catalysis; coumarins; Pechmann condensation; catalyst characterization; ammonia-TPD;

D O I：

10.1016/j.molcata.2006.05.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel SO42-/CexZr1-xO2 catalyst has been employed for Pechmann condensation of phenols under solvent-free conditions. Catalyst loads as low as 10 wt. % could be used leading to high yields with activated phenols at an oil bath temperature of 393 K. To make the catalyst, Ce-Zr-hydroxide gel was prepared by a coprecipitation method and SO42- ions were deposited by treating the gel with sulfuric acid and calcined at 923 K. Surface and bulk properties of the catalyst was investigated by means of X-ray powder diffraction, ammonia-temperature programmed desorption, Raman spectroscopy, and BET surface area methods. Characterization results reveal the super acidic nature of the catalyst. The methodology presented offers significant improvements for the synthesis of coumarins with regard to yield of products, simplicity in. operation, and green aspects by avoiding toxic conventional catalysts and solvents. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：290 / 294

页数：5

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