CH3NH3SnxPb(1-x)I3 Perovskite Solar Cells Covering up to 1060 nm

被引:875
作者
Ogomi, Yuhei [1 ]
Morita, Atsushi [1 ]
Tsukamoto, Syota [1 ]
Saitho, Takahiro [1 ]
Fujikawa, Naotaka [1 ]
Shen, Qing [2 ,4 ]
Toyoda, Taro [2 ,4 ]
Yoshino, Kenji [3 ,4 ]
Pandey, Shyam S. [1 ]
Ma, Tingli [1 ]
Hayase, Shuzi [1 ,4 ]
机构
[1] Kyushu Inst Technol, Grad Sch Life Sci & Syst Engn, Wakamatsu Ku, Kitakyushu, Fukuoka 8080196, Japan
[2] Univ Electrocommun, Grad Sch Informat & Engn, Chofu, Tokyo 1828585, Japan
[3] Miyazaki Univ, Dept Elect & Elect Engn, Miyazaki 8892192, Japan
[4] Japan Sci & Technol Agcy JST, CREST, Kawaguchi, Saitama 3320012, Japan
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2014年 / 5卷 / 06期
关键词
EFFICIENT; TIN; HALIDES;
D O I
10.1021/jz5002117
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report photovoltaic performances of all-solid state Sn/Pb halide-based perovskite solar cells. The cell has the following composition: F-doped SnO2 layered glass/compact titania layer/porous titania layer/CH3NH3SnxPb(1-x)I3/regioregular poly(3-hexylthiophene-2,5-diyl). Sn halide perovskite itself did not show photovoltaic properties. Photovoltaic properties were observed when PbI2 was added in SnI2. The best performance was obtained by using CH3NH3Sn0.5Pb0.5I3 perovskite. 4.18% efficiency with open circuit voltage 0.42 V, fill factor 0.50, and short circuit current 20.04 mA/cm(2) are reported. The edge of the incident photon to current efficiency curve reached 1060 nm, which was 260 nm red-shifted compared with that of CH3NH3PbI3 perovskite solar cells.
引用
收藏
页码:1004 / 1011
页数:8
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