Shape-persistent aromatic amide oligomers: New tools for supramolecular chemistry

被引：181

作者：

Li, Zhan-Ting ^{[1
]}

Hou, Jun-Li ^{[1
]}

Li, Chuang ^{[1
]}

Yi, Hui-Ping ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod, Shanghai 200032, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2006年 / 1卷 / 06期

关键词：

amides; foldamers; hydrogen bonds; molecular recognition; self-assembly;

D O I：

10.1002/asia.200600186

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With an increasing number of folding and helical structures available, chemists have begun to pay greater attention to the functions of this family of structurally unique oligomers. Hydrogen-bonding-mediated aromatic oligoamide foldamers have the features of good structural predictability, synthetic facility, and structural modification, which make them very promising as scaffolds or platforms for supramolecular chemistry. Recent advances in the applications of this class of shape-persistent oligomers in the promoted synthesis of macrocycles, design of new nonring receptors, supramolecular self-assembly, molecular encapsulation, and reaction acceleration, are highlighted in this Focus Review.

引用

页码：766 / 778

页数：13

共 76 条

[71] Helical aromatic oligoamides: Reliable, readily predictable folding from the combination of rigidified structural motifs [J].