Preparation and characterization of polythiophene/molybdenum disulfide intercalation material

被引：57

作者：

Lin, Bi-Zhou ^{[1
]}

Ding, Cong ^{[1
]}

Xu, Bai-Huan ^{[1
]}

Chen, Zhi-Jian ^{[1
]}

Chen, Yi-Lin ^{[1
]}

机构：

[1] Huaqiao Univ, Dept Appl Chem, Key Lab Funct Mat Fujian Higher Educ, Quanzhou 362021, Peoples R China

来源：

MATERIALS RESEARCH BULLETIN | 2009年 / 44卷 / 04期

关键词：

Layered compounds; Intercalation reactions; X-ray diffraction; Electrical properties; TRANSITION-METAL DICHALCOGENIDES; MOLYBDENUM-DISULFIDE; POLY(ETHYLENE OXIDE); INORGANIC MATERIALS; LAYER MOS2; NANOCOMPOSITES; CONDUCTIVITY; MONTMORILLONITE; POLYMERIZATION; COMPLEXES;

D O I：

10.1016/j.materresbull.2008.09.031

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Utilizing the solvothermal synthesis technique, lithium intercalated molybdenum disulfide Li(x)MoS(2) Was expediently obtained, which was allowed to react with water to the formation of single-molecule-layer suspension. The intercalation of polythiophene into MoS(2) was achieved by means of in situ polymerization of the intercalated monomers. The nanocomposite was characterized by X-ray powder diffraction, thermogravimertic analysis and differential scanning calorimetry. it was revealed that the intercalated polymer chain favors the monolayer arrangement with the thiophene rings lying parallel with the host layers. The optimum conditions were explored to prepare the single-phase product with a composition of Li(0.12)(PTP)(0.54)MoS(2). The nanocomposite exhibits enhanced electrical conductivity in the order of 10(-2) S cm(-1) at ambient temperature, resulted from the incorporation of the electronically conductive polythiophene between the semiconducting host layers and the coupling between the guest conjugated pi-orbits and the host layers. (C) 2009 Published by Elsevier Ltd.

引用

页码：719 / 723

页数：5

共 43 条

[21] Synthesis of new oligothiophene derivatives and their intercalation compounds: orientation effects [J].