When Z′=2 is better than Z′=1-supramolecular centrosymmetric hydrogen-bonded dimers in chiral systems

被引：90

作者：

Anderson, Kirsty M.

Afarinkia, Kamyar

Yu, Hiu-wan

Goeta, Andres E.

Steed, Jonathan W.

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Kings Coll London, Dept Chem, London WC2R 2LS, England

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/cg0603265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High Z' structures can be engineered by combining a molecule with one (or more) resolved chiral center(s) with a strongly directional supramolecular synthon with a preference for centrosymmetry because, in order to preserve the dimer motif, one or more extra molecules must be introduced into the asymmetric unit.

引用

收藏

页码：2109 / 2113

页数：5

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