Supramolecular assemblies of hydrogen-bonded carboxylic acid dimers mediated by phenyl-pentafluorophenyl stacking interactions

被引：110

作者：

Gdaniec, M

Jankowski, W

Milewska, MJ

Poloñski, T

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

[2] Univ Gdansk, Dept Chem, PL-80952 Gdansk, Poland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 33期

关键词：

crystal engineering; hydrogen bonds; pi interactions; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200351432

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stacks of acids: Pentafluorobenzoic acid forms heterodimers with benzoic acid and 2,4,6-trimethylbenzoic acid that assemble into π stacks with alternating phenyl and pentafluorophenyl residues (see picture). Cocrystals of these acids with 1,4-bisarylbutadiynes contain acid homodimers sandwiched between the diacetylene molecules.

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收藏

页码：3903 / 3906

页数：4

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