Palladium/Lewis acid catalyzed desymmetrization of fulvene-derived bicyclic hydrazines: A facile synthesis of substituted alkylidene cyclopentenes

被引：18

作者：

Anas, S. ^{[1
]}

Sajisha, V. S. ^{[1
]}

Mohanlal, Smitha ^{[1
]}

Radhakrishnan, K. V. ^{[1
]}

机构：

[1] CSIR, Reg Res Lab, Organ Chem Sect, Chem Sci & Technol Div, Trivandrum 695019, Kerala, India

来源：

SYNLETT | 2006年 / 15期

关键词：

fulvenes; bicyclic hydrazines; alkylidene cyclopentenes; organostarmanes; Lewis acids;

D O I：

10.1055/s-2006-950402

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Desymmetrization of fulvene-derived bicyclic hydrazines by a palladium/Lewis acid catalyzed reaction with allyl and vinyl stannanes leading to the efficient synthesis of synthetically important alkylidene cyclopentenes is described.

引用

页码：2399 / 2402

页数：4

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