Solvent-free oxidation of benzyl alcohol to benzaldehyde by tert-butyl hydroperoxide using transition metal containing layered double hydroxides and/or mixed hydroxides

被引：117

作者：

Choudhary, VR ^{[1
]}

Dumbre, DK ^{[1
]}

Uphade, BS ^{[1
]}

Narkhede, VS ^{[1
]}

机构：

[1] Natl Chem Lab, Div Chem Engn, Pune 411008, Maharashtra, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 215卷 / 1-2期

关键词：

oxidation of benzyl alcohol to benzaldehyde; transition metal containing hydrotalcite-like catalysts; solvent-free oxidation of benzyl alcohol;

D O I：

10.1016/j.molcata.2004.01.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Performance of Mn-Al, Co-Al, Ni-Al, Zn-Al, Mg-Fe, Mn-Fe, Co-Fe, Ni-Fe, Mn-Cr, Co-Cr, Ni-Cr, Cu-Cr, and Zn-Cr layered double hydroxides (LDH) and/or mixed hydroxides (HD) solid catalysts has been evaluated for the liquid phase oxidation of benzyl alcohol to benzaldehyde using TBHP as an oxidizing agent in the absence of any solvent. The Mn, Cu, and Co containing LDH solids show good catalytic activity in the oxidation and hence these are promising catalysts for the solvent-free oxidation of benzyl alcohol to benzaldehyde. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：129 / 135

页数：7

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