Synthesis of a phosphorus-containing hybrid porphyrin

被引：51

作者：

Matano, Yoshihiro ^{[1
]}

Nakabuchi, Takashi

Miyajima, Tooru

Imahori, Hiroshi

Nakano, Haruyuki

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 25期

关键词：

D O I：

10.1021/ol0622763

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A phosphorus-containing hybrid porphyrin was successfully prepared via the BF3-promoted dehydrative condensation between sigma(4)-phosphatripyrrane and 2,5-bis[hydroxy(phenyl)methyl]thiophene. The NMR and UV-vis absorption spectra, electrochemical measurements, and DFT calculations revealed that the sigma(3)-P,N-2,S-hybrid porphyrin exhibits high aromaticity as an 18 pi-electron system in terms of both geometric and magnetic criteria.

引用

页码：5713 / 5716

页数：4

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