Reactivity of Mg-Ba catalyst in NOx storage/reduction
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作者:
Basile, F.
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Univ Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, ItalyUniv Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, Italy
Basile, F.
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Fornasari, G.
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Univ Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, ItalyUniv Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, Italy
Fornasari, G.
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Gambatesa, A.
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Univ Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, ItalyUniv Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, Italy
Gambatesa, A.
[1
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Livi, M.
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Univ Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, ItalyUniv Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, Italy
Livi, M.
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Vaccari, A.
[1
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[1] Univ Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, Italy
A new catalyst for NOx storage/reduction was prepared to improve the activity of Ba-Pt/gamma-Al2O3 by replacing Ba with a mixture of Ba and Mg. The catalyst was prepared by impregnating I wt.% Pt and then the alkaline-earth metals (Mg, Ba) on commercial gamma-Al2O3. The tests have been carried out in a wide temperature range (ca. 200-400 degrees C) in order to understand the role of the mixture of alkaline-earth metals as a function of temperature. The behaviour of the two catalysts was different and indicated a synergetic effect between Mg and Ba. (c) 2006 Elsevier B.V. All rights reserved.