Reactivity of Mg-Ba catalyst in NOx storage/reduction

被引:14
作者
Basile, F. [1 ]
Fornasari, G. [1 ]
Gambatesa, A. [1 ]
Livi, M. [1 ]
Vaccari, A. [1 ]
机构
[1] Univ Bologna, Dipartimento Chim Ind & Mat, Alma Mater Studiorum, I-40136 Bologna, Italy
关键词
NSR; NOx storage/reduction; alkaline-earth metal; Pt;
D O I
10.1016/j.cattod.2006.08.051
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A new catalyst for NOx storage/reduction was prepared to improve the activity of Ba-Pt/gamma-Al2O3 by replacing Ba with a mixture of Ba and Mg. The catalyst was prepared by impregnating I wt.% Pt and then the alkaline-earth metals (Mg, Ba) on commercial gamma-Al2O3. The tests have been carried out in a wide temperature range (ca. 200-400 degrees C) in order to understand the role of the mixture of alkaline-earth metals as a function of temperature. The behaviour of the two catalysts was different and indicated a synergetic effect between Mg and Ba. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 63
页数:5
相关论文
共 25 条
[1]   Influence of the type of reducing agent (H2, CO, C3H6 and C3H8) on the reduction of stored NOX in a Pt/BaO/Al2O3 model catalyst [J].
Abdulhamid, H ;
Fridell, E ;
Skoglundh, M .
TOPICS IN CATALYSIS, 2004, 30-1 (1-4) :161-168
[2]   NOx release from a noble metal/BaO catalyst:: dependence on gas composition [J].
Amberntsson, A ;
Persson, H ;
Engström, P ;
Kasemo, B .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2001, 31 (01) :27-38
[3]   A transient kinetic study of the mechanism of the NO+H2 reaction over Pt/SiO2 catalysts -: 1.: Isotopic transient kinetics and temperature programmed analysis [J].
Burch, R ;
Shestov, AA ;
Sullivan, JA .
JOURNAL OF CATALYSIS, 1999, 186 (02) :353-361
[4]   Study of the effect of Ba loading for catalytic activity of Pt-Ba/Al2O3 model catalysts [J].
Castoldi, L ;
Nova, I ;
Lietti, L ;
Forzatti, P .
CATALYSIS TODAY, 2004, 96 (1-2) :43-52
[5]   Nanostructured catalysts for NOx storage-reduction and N2O decomposition [J].
Centi, G ;
Arena, GE ;
Perathoner, S .
JOURNAL OF CATALYSIS, 2003, 216 (1-2) :443-454
[6]   NOx storage-reduction catalysts based on hydrotalcite -: Effect of Cu in promoting resistance to deactivation [J].
Centi, G ;
Fornasari, G ;
Gobbi, C ;
Livi, M ;
Trifirò, F ;
Vaccari, A .
CATALYSIS TODAY, 2002, 73 (3-4) :287-296
[7]   NOx storage-reduction over Pt/Mg-Al-O catalysts with different Mg/Al atomic ratios [J].
Cheng, H ;
Chen, GW ;
Wang, SD ;
Wu, DY ;
Zhang, Y ;
Li, HQ .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2004, 21 (03) :595-600
[8]   Pt-free sulphur resistant NOx traps [J].
Clacens, JM ;
Montiel, R ;
Kochkar, H ;
Figueras, F ;
Guyon, M ;
Beziat, JC .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 53 (01) :21-27
[9]   NOx storage in barium-containing catalysts [J].
Fridell, E ;
Skoglundh, M ;
Westerberg, B ;
Johansson, S ;
Smedler, G .
JOURNAL OF CATALYSIS, 1999, 183 (02) :196-209
[10]  
HECK RM, 1995, CATALYTIC AIR POLLUT