Electrocatalysis:: understanding the success of DSA®

被引：760

作者：

Trasatti, S ^{[1
]}

机构：

[1] Univ Milan, Dept Phys Chem & Electrochem, I-20133 Milan, Italy

来源：

ELECTROCHIMICA ACTA | 2000年 / 45卷 / 15-16期

关键词：

dimensionally stable anodes (DSA); industrial processes; electrocatalysis; oxide electrodes; chlorine evolution;

D O I：

10.1016/S0013-4686(00)00338-8

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The 'legend' of DSA(R) (Dimensionally Stable Anodes), one of the greatest technological breakthrough of the past 50 years of electrochemistry, is reviewed with the aim to emphasise the reasons for their success. In this respect, the industrial success, which came first, was due to factors differing from those responsible for the successive boom of fundamental research on the same materials. This article scrutinises these factors highlighting the aspects which make these materials so much intriguing. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2377 / 2385

页数：9

共 94 条

[51] INSITU IDENTIFICATION OF RUO4 AS THE CORROSION PRODUCT DURING OXYGEN EVOLUTION ON RUTHENIUM IN ACID-MEDIA [J].

KOTZ, R ;

STUCKI, S ;

SCHERSON, D ;

KOLB, DM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 172 (1-2) :211-219

[52] STABILIZATION OF RUO2 BY IRO2 FOR ANODIC OXYGEN EVOLUTION IN ACID-MEDIA [J].

KOTZ, R ;

STUCKI, S .

ELECTROCHIMICA ACTA, 1986, 31 (10) :1311-1316

[53] NEW DEVELOPMENTS AND APPLICATIONS OF COATED TITANIUM ANODES [J].

KOZIOL, KR ;

SIEBERER, KH ;

RATHJEN, HC ;

ZENK, JB ;

WENK, EF .

CHEMIE INGENIEUR TECHNIK, 1977, 49 (04) :288-293

[54] KINETICS AND MECHANISM OF ANODIC CHLORINE AND OXYGEN EVOLUTION REACTIONS ON TRANSITION-METAL OXIDE ELECTRODES [J].

KRISHTALIK, LI .

ELECTROCHIMICA ACTA, 1981, 26 (03) :329-337

[55]

KRISHTALIK LI, 1979, ELEKTROKHIMIYA, V15, P462

[56] CATHODIC BEHAVIOR OF RUO2-DOPED NI/CO3O4 ELECTRODES IN ALKALINE-SOLUTIONS - SURFACE CHARACTERIZATION [J].

KRSTAJIC, N ;

TRASATTI, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (08) :2675-2681

[57]

Kuhn A.T., 1971, Industrial Electrochemical Processes

[58] RUTHENIUM DIOXIDE-BASED FILM ELECTRODES .3. EFFECT OF CHEMICAL COMPOSITION AND SURFACE MORPHOLOGY ON OXYGEN EVOLUTION IN ACID-SOLUTIONS [J].

LODI, G ;

SIVIERI, E ;

DEBATTISTI, A ;

TRASATTI, S .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1978, 8 (02) :135-143

[59] KINETICS OF CORROSION OF RUTHENIUM DIOXIDE HYDRATE BY BROMATE IONS UNDER ACIDIC CONDITIONS [J].

MILLS, A ;

DAVIES, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (06) :955-958

[60]

MORIMOTO T, 2000, IN PRESS ELECTROCHIM, V45

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