Facile synthesis of V6O13 micro-flowers for Li-ion and Na-ion battery cathodes with good cycling performance

被引:57
作者
Fei, Hailong [1 ]
Lin, Yunsheng [1 ]
Wei, Mingdeng [1 ]
机构
[1] Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Peoples R China
基金
美国国家科学基金会;
关键词
Vanadium oxide; Lithium-ion battery; Sodium-ion battery; Hydrothermal; Oxalic acid; Nitrate; Ammonium metavanadate; VANADIUM-OXIDES; LITHIUM; INTERCALATION; ELECTROLYTE; V2O5;
D O I
10.1016/j.jcis.2014.03.028
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple and versatile method for the preparation of V6O13 microflowers is developed via a simple hydrothermal route with the aid of an alkali metal nitrate salt, which has important effects on the formation of V6O13. It is found that V6O13 microflowers display good cycling stability as cathode materials for lithium-ion battery. In addition, they show high capacities for sodium-ion battery. We have V6O13 microflowers discharge capacities up to 225.7 mA h g(-1) for sodium-ion battery. The reason may be the fewer phase transitions occurring upon lithium and sodium insertion for phase-unpure V6O13 microflowers. (C) 2014 Elsevier Inc. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
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