Solar photocatalytic degradation of eight commercial dyes in TiO2 suspension

被引:183
作者
Wang, YZ [1 ]
机构
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, State Key Lab Environm Aquat Chem, Beijing 100085, Peoples R China
关键词
solar photocatalysis; commercial dyes; decolorization; mineralization; degradation pattern; TiO2;
D O I
10.1016/S0043-1354(99)00210-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The photocatalytic degradation of eight commercial dyes with different structure and containing different substitute groups has been investigated using TiO2 as photocatalyst in aqueous solution under solar irradiation. Decolorization rate, TOC decrease and inorganic ion production of the dye solution were detected. The experimental results indicate that eight commercial dyes could be degradated efficiently at different levels. The comparison of chloride and sulfate ions production rare from the cleavage of substitute groups in different structure positions reveals the dye compounds degradation pattern and decomposition pathway. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:990 / 994
页数:5
相关论文
共 11 条
[1]  
ALEKABI H, 1991, INT J ENVIRON POLLUT, V1, P125
[2]  
[Anonymous], P 35 PURD IND WAST C
[3]  
Blake D.M., 1994, Bibliography of Work on the Photocatalytic Removal of Hazardous Compounds from Water and Air
[4]  
DAOXIN Y, 1994, J ENVIRON SCI, V6, P244
[5]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96
[6]   Decolorization and biodegradability of dyeing wastewater treated by a TIO2-sensitized photo-oxidation process [J].
Li, XZ ;
Zhang, M .
WATER SCIENCE AND TECHNOLOGY, 1996, 34 (09) :49-55
[7]  
LINDNER M, 1995, SOLAR ENG, P399
[8]   Large solar plant photocatalytic water decontamination: Effect of operational parameters [J].
Minero, C ;
Pelizzetti, E ;
Malato, S ;
Blanco, J .
SOLAR ENERGY, 1996, 56 (05) :421-428
[9]   LARGE SOLAR PLANT PHOTOCATALYTIC WATER DECONTAMINATION - DEGRADATION OF PENTACHLOROPHENOL [J].
MINERO, C ;
PELIZZETTI, E ;
MALATO, S ;
BLANCO, J .
CHEMOSPHERE, 1993, 26 (12) :2103-2119
[10]  
SHENG HL, 1993, WATER RES, V27, P1743