Recent advances in f element reduction chemistry

被引：66

作者：

Evans, WJ ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 652卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

lanthanide; actinide; organometallic; reduction; steric crowding;

D O I：

10.1016/S0022-328X(02)01308-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One of the most rapidly changing frontiers in organometallic chemistry involves the reductive chemistry of organolanthanide and organoactinide complexes. This contribution summarizes recent advances in this area arising from newly available divalent lanthanide systems and the sterically crowded (C5Me4)(3)M complexes as presented at the 'Frontiers in Organometallic Chemistry Symposium' at the National Meeting of the American Chemical Society in Chicago in August 2001. (C) 2002 Published by Elsevier Science B.V.

引用

页码：61 / 68

页数：8

共 110 条

[1] REVERSIBLE OPENING AND CLOSING OF HETERO TRIMETALLIC UNITS IN (C5H5)2Y(THF)RE2H7(PME2PH)4 AND (C5H5)2LURE2H7(PME2PH)4 [J].